α-Hexylcinnamaldehyde
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α-Hexylcinnamaldehyde

α-Hexylcinnamaldehyde's cas code is 101-86-0

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Product Description

α-Hexylcinnamaldehyde Basic information


Product Name:

α-Hexylcinnamaldehyde

Synonyms:

FEMA 2569;HCA;JASMONAL H;HEXYLCINNAMALDEHYDE;HEXYL CINNAMIC ALDEHYDE;A-N-HEXYL-B-PHENYLACROLEIN;ALPHA-HEXYLCINNAMIC ALDEHYDE;ALPHA-HEXYLCINNAMALDEHYDE

CAS:

101-86-0

MF:

C15H20O

MW:

216.32

EINECS:

202-983-3

Product Categories:

Pharmaceutical Intermediates;aldehyde Flavor;Aldehydes;C10 to C21;Carbonyl Compounds;Alphabetical Listings;Flavors and Fragrances;G-H

Mol File:

101-86-0.mol



α-Hexylcinnamaldehyde Chemical Properties


Boiling point 

174-176 °C15 mm Hg(lit.)

density 

0.95 g/mL at 25 °C(lit.)

FEMA 

2569 | ALPHA-HEXYLCINNAMALDEHYDE

refractive index 

n20/D 1.55(lit.)

Fp 

200 °F

storage temp. 

2-8°C

solubility 

water: soluble0.005g/L at 25°C

JECFA Number

686

CAS DataBase Reference

101-86-0(CAS DataBase Reference)

NIST Chemistry Reference

Octanal, 2-(phenylmethylene)-(101-86-0)

EPA Substance Registry System

.alpha.-Hexylcinnamaldehyde (101-86-0)


α-Hexylcinnamaldehyde Safety Information


Hazard Codes 

C,Xi

Risk Statements 

36/37/38-34-43-52/53

Safety Statements 

26-36/37/39-45-36-36/37-61

RIDADR 

UN 3265 8/PG 3

WGK Germany 

2

RTECS 

GD6560000

HS Code 

29122990


α-Hexylcinnamaldehyde Usage And Synthesis


Description

α-Hexylcinnamaldehyde has a jasmine-like odor, particularly on dilution. May be synthesized by condensation of octylaldehyde with benzaldehyde.

Chemical Properties

Hexyl cinnamaldehyde has a jasmine-like odor, particularly on dilution.

Chemical Properties

alpha-Hexylcinnamaldehyde is a yellow liquid with a mild, slightly fatty, floral, somewhat herbal odor, and a distinct jasmine note. Similarly to the ??-amyl homolog, ??-hexylcinnamaldehydemust be protected against oxidation by the addition of stabilizers. It is prepared in a manner similar to that of ??-amylcinnamaldehyde by alkaline condensation of excess benzaldehyde with octanal (instead of heptanal). ??-Hexylcinnamaldehyde is widely used in flower compositions (e.g., jasmine and gardenia) and, because of its stability to alkali, in soap perfumes.

Chemical Properties

Pale-yellow liquid; jasminelike odor, particularly on dilution. Soluble in most fixed oils and in mineral oil; insoluble in glycerol and in propylene glycol.

Occurrence

Reported found in cooked, scented rice.

Uses

hexyl cinnamal is also known as hexyl cinnamic aldehyde. It is a fragrance that provides a floral, jasmine-like scent.

Uses

α-Hexylcinnamaldehyde is characterized by a typical floral scent, which makes them suitable to be used as fragrances in personal care (perfumes, creams, shampoos, etc.) and household products. It has been also used as flavouring additive in food and pharmaceutical industry.

Definition

ChEBI: A member of the class of cinnamaldehydes carrying a hexyl substituent at the alpha-position.

Preparation

By condensation of octylaldehyde with benzaldehyde

Taste threshold values

Taste characteristics at 5 ppm: sweet, waxy, floral, green, citrus and fruity nuances

Hazard

Combustible.

Contact allergens

Hexyl cinnamic aldehyde is a fragrance allergen. Its presence has to be mentioned by name in cosmetics within the EU.


α-Hexylcinnamaldehyde Preparation Products And Raw materials


Raw materials

Benzaldehyde-->Amylcinnamaldehyde-->Octanal


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